Article

Synthesis of Janus Particles via Strain-Driven Microphase Separation and Their Assembly into Nanoscale Vesicles

State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P. R. China
Ian Wark Research Institute, University of South Australia, Adelaide, South Australia 5095, Australia
ACS Nano, 2014, 8 (11), pp 11206–11213
DOI: 10.1021/nn503382v
Publication Date (Web): October 23, 2014
Copyright © 2014 American Chemical Society
*Address correspondence to hbxia@sdu.edu.cn, Dayang.Wang@unisa.edu.au.

Abstract

Abstract Image

Janus particles, consisting of Fe3O4 nanoparticles and organic particles of the complexes of α-cyclodextrin and polyethylene glycol (5) nonylphenyl ether, have been successfully fabricated via strain-driven microphase separation, which is distinct from conventional surface wetting-driven microphase separation. The as-prepared Janus particles can self-assemble into hollow spheres, which draw a clear analogy with self-assembly of lipids to vesicles.

Supporting Information


Selected area diffraction pattern, FTIR spectrum and Mössbauer spectra of as-prepared Fe3O4/α-CD-NPE5 Janus particles and additional TEM images. This material is available free of charge via the Internet at http://pubs.acs.org.

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Article Views: 1,588 Times
Received 23 June 2014
Date accepted 23 October 2014
Published online 23 October 2014
Published in print 25 November 2014
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